Old Syllabus - Engineering Chemistry
- Electro-chemistry and Buffer(6 hours)
- Electro-Chemical cells
- Electrode Potential and Standard Electrode Potential
- Measurement of Electrode Potential
- Nernst equation
- EMF of Cell
- Application of Electrochemical and Electrolytic cells
- Electrochemical Series and its Application
- Buffer: Its type and mechanism
- Henderson’s equation for pH of buffer and related problems
- Corrosion and its type
- Factors influencing Corrosion
- Prevention of Corrosion
- Catalyst(4 hours)
- Introduction
- Action of Catalyst(Catalytic Promoters and Catalytic Poisons)
- Characteristics of Catalyst
- Types of Catalyst
- Theories of Catalysis
- Industrial Applications of Catalysts
- Environmental Chemistry(5 hours)
- Air Pollution
- Air Pollutants i) Gases:SOx, NOx, CO, CO2, O3 and Hydrocarbons ii)Particulates dust, smoke and fly ash
- Effects of Air Pollutants on human beings and their possible remedies
- Ozone depletion and its Photochemistry
- Water Pollution(Ref of Surface Water and Pond Water)
- Water Pollutants(Ref of Surface Water), their adverse effect and remedies
- Soil Pollution
- Pollutants of Soil, their adverse effects and possible remedies
- Engineering Polymers(6 hours)
- Inorganic Polymers
- General properties of Inorganic Polymers
- Polyphosphazines
- Sulpher Based Polymers
- Chalcogenide Glasses
- Silicones
- Organic Polymers
- Types of Organic Polymers
- Preparation and application of
i) Polyurethane ii) Polystyrene iii) Polyvinylchloride iv) Teflon v) Nylon 6,6 and vi) Bakelite vii) Epoxy Resin viii) Fiber Reinforced Polymer
- Concept of Bio-Degradable, Non-Biodegradable and Conducting polymers
- 3-d Transition elements and their applications(5 hours)
- Introduction
- Electronic Configuration
- Variable Oxidation states
- Complex formation tendency
- Color formation
- Magnetic properties
- Alloy formation
- Applications of 3-d transition elements
- Coordination Complexes(5 hours)
- Introduction
- Terms used in Coordination Complexes
- Werner’s Theory Coordination Complexes
- Sidgwick’s Model and Sidgwick’s effective atomic number rule
- Nomenclature of Coordination compounds(Neutral type, simple cation and complex anion and complex cation and simple anion type)
- Valence Bond Theory of Complexes
- Application of valence bond theory in the formation of i) Tetrahedral Complexes
ii) Square planar Complexes and iii) Octahedral Complexes
- Limitations of Valence Bond Theory
- Applications of Coordination Complexes
- Explosives(3 hours)
- Introduction
- Types of explosives: Primary, Low and High explosives
- Preparation and application of TNT, TNG, Nitrocellulose and Plastic explosives
- Lubricants and Paints(2 hours)
- Introduction
- Function of Lubricants
- Classification of Lubricants(Oils, Greases and Solid)
- Paints
- Types of Paint
- Application of Paints
- Stereochemistry(4 hours)
- Introduction
- Geometrical Isomerism(Cis-Trans Isomerism), Z and E concept of Geometrical Isomerism
- Optical Isomerism with reference to two asymmetrical carbon center molecules
- Terms Optical activity, Enantiomers, Diastereomers, Meso structures, Racemic mixture and Resolution
- Reaction Mechanism in Organic reactions(4 hours)
- Substitution reaction
- Types of substitution reaction SN1 and SN2
- Elimination reaction
- Types of elimination reaction E1 and E2
- Factors governing SN1, SN2, E1 and E2 reaction mechanism path